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VALOX™ FR Resin ENH3500

Chemical Family
Polyesters

SABIC's Specialties Business VALOX™ ENH3500 is an unreinforced, non-chlorinated/brominated flame retardant Polybutylene Terephthalate (PBT) injection moldable grade with excellent chemical resistance. It has a UL94V0@0.80mm flame rating. This is a good candidate for a variety of applications needing a sustainable FR PBT solution.

Product families

Applications

Applications
  • Consumer Goods — Furniture
Electrical & Electronics — Parts & Components
  • Connectors
  • Switches & Relays
  • Terminal Blocks Plugs & Sockets
Electrical & Electronics — Wire & Cable
  • Jacketing & Insulation

Product Families

Plastics — Engineering & Specialty Polymers
  • Polyesters & Copolyesters

Other characteristics

Brand
VALOX™ FR Resin
Polymer Name
Polybutylene Terephthalate (PBT)
Flexural Modulus
2700.0 - 2700.0 MPa
Additives Included
Flame Retardant
Processing Methods
Injection Molding
Note

ʰ Measurements made from laboratory test coupon. Actual shrinkage may vary outside of range due to differences in processing conditions, equipment, part geometry and tool design. It is recommended that mold shrinkage studies be performed with surrogate or legacy tooling prior to cutting tools for new molded article.; ᵖ UL ratings shown on the technical datasheet might not cover the full range of thicknesses and colors. For details, please see the UL Yellow Card.; ⁷ Injection Molding parameters are only mentioned as general guidelines. These may not apply or may need adjustment in specific situations such as low shot sizes, large part molding, thin wall molding and gas-assist molding.; ¹¹ The information stated on Technical Datasheets should be used as indicative only for material selection purposes and not be utilized as specification or used for part or tool design.

Markets
  • Consumer Goods
  • Electrical & Electronics
Flame Rating
  • UL 94 5VA
  • UL 94 5VB
  • UL 94 V0
Technology
Plastics
Labeling Claims
  • Bromine-free
  • Chlorine-free
  • Confirms to ECO-Label
Material Features
  • Chemical Resistant
  • Flame Retardant
  • Non-brominated
  • Non-chlorinated
  • Unreinforced
Country Availability
  • Canada
  • China (Mainland)
  • Mexico
  • USA
Certifications and Compliance
UL 94
Plastics and Elastomers End Uses
  • Cables
  • Connectors
  • Electrical Components
  • Electrical/Electronic Applications
  • Electronic Components
  • Furniture
  • Medical Device Housings
  • Medical/Healthcare Applications
Plastics and Elastomers Functions
Resin
Plastics and Elastomers Processing Methods
Injection Molding

Technical data

Table 1 of 7

9 rows
CharacteristicValueUnitMethod
Moisture Absorption (at 23°C, 50% RH, 24hrs) ¹¹0.08%ASTM D570
Water Absorption (at 23°C, 24hrs) ¹¹0.35%ASTM D570
Water Absorption (at 23°C, 24hrs) ¹¹3.50E-01%ASTM D570
Specific Gravity ¹¹1.31—ASTM D792
Mold Shrinkage (on Tensile Bar, flow) ʰ ¹¹1.8 - 2.8%SABIC method
Density ¹¹1.31g/cm³ISO 1183
Melt Volume Rate (at 250°C, 2.16 kg) ¹¹20cm³/10 minISO 1133
Moisture Absorption (at 23°C, 50% RH) ¹¹0.08%ISO 62
Water Absorption (at 23°C, saturated) ¹¹0.35%ISO 62-1

Table 2 of 7

14 rows
CharacteristicValueUnitMethod
Tensile Stress (Yield, Type I, 50 mm/min) ¹¹44MPaASTM D638
Tensile Stress (Break, Type I, 50 mm/min) ¹¹42MPaASTM D638
Tensile Strain (Yield, Type I, 50 mm/min) ¹¹3%ASTM D638
Tensile Strain (Break, Type I, 50 mm/min) ¹¹10%ASTM D638
Tensile Modulus (at 5 mm/min) ¹¹3150MPaASTM D638
Flexural Stress (Yield, 1.3 mm/min, 50 mm span) ¹¹77MPaASTM D790
Flexural Modulus (at 1.3 mm/min, 50 mm span) ¹¹2750MPaASTM D790
Tensile Stress (Yield, 50 mm/min) ¹¹39MPaISO 527
Tensile Stress (Break, 50 mm/min) ¹¹38MPaISO 527
Tensile Strain (Yield, 50 mm/min) ¹¹3%ISO 527
Tensile Strain (Break, 50 mm/min) ¹¹8%ISO 527
Tensile Modulus (at 1 mm/min) ¹¹3200MPaISO 527

Table 3 of 7

14 rows
CharacteristicValueUnitMethod
Heat Deflection Temperature (at 0.45 MPa, 3.2 mm, Unannealed) ¹¹160°CASTM D648
Coefficient of Thermal Expansion (at -40°C to 95°C, flow) ¹¹8.00E-051/°CASTM E831
Coefficient of Thermal Expansion (at -40°C to 95°C, flow) ¹¹0.000081/°CASTM E831
Coefficient of Thermal Expansion (at -40°C to 95°C, xflow) ¹¹0.000081/°CASTM E831
Heat Deflection Temperature (at 1.82 MPa, 3.2mm, Unannealed) ¹¹60°CASTM D648
Vicat Softening Temperature (Rate B/50) ¹¹170°CASTM D1525
Vicat Softening Temperature (Rate B/50) ¹¹170°CISO 306
Ball Pressure Test (at 123°C to 127°C) ¹¹Pass—IEC 60695-10-2
Vicat Softening Temperature (Rate B/120) ¹¹170°CISO 306
Heat Deflection Temperature/Af (at 1.8 Mpa, Flatw 80*10*4, sp=64mm) ¹¹60°CISO 75/Af
Heat Deflection Temperature/Bf (at 0.45 Mpa, Flatw 80*10*4, sp=64mm) ¹¹160°CISO 75/Bf
Relative Temperature Index (Electrical) ᵖ ¹¹150°CUL 746B

Table 4 of 7

9 rows
CharacteristicValueUnitMethod
Comparative Tracking Index (UL, PLC) ¹¹0PLC CodeUL 746A
Comparative Tracking Index ᵖ ¹¹525VIEC 60112
Hot Wire Ignition (PLC 2) ¹¹min. 3mmUL 746A
Hot Wire Ignition (PLC 3) ¹¹min. 1.5mmUL 746A
Hot Wire Ignition (PLC 4) ¹¹min. 0.8mmUL 746A
Volume Resistivity ¹¹min. 1.E+15Ω.cmIEC 60093
Volume Resistivity ¹¹min. 1.E+15Ω.cmASTM D257
High Ampere Arc Ignition (PLC 0) ¹¹min. 0.8mmUL 746A
Surface Resistivity (ROA) ¹¹min. 1.E+15ΩIEC 60093

Table 5 of 7

8 rows
CharacteristicValueUnitMethod
Izod Impact (Notched, at 23°C) ¹¹40J/mASTM D256
Izod Impact (Unnotched, at 23°C) ¹¹No breakJ/mASTM D4812
Izod Impact (Notched, 80*10*4, at 23°C) ¹¹5kJ/m²ISO 180/1A
Izod Impact (Notched, 80*10*4, at -30°C) ¹¹5kJ/m²ISO 180/1A
Izod Impact (Unnotched, 80*10*4, at 23°C) ¹¹No breakkJ/m²ISO 180/1U
Izod Impact (Unnotched, 80*10*4, at -30°C) ¹¹No breakkJ/m²ISO 180/1U
Charpy Impact (at 23°C, V-notch Edgew 80*10*4 sp=62mm) ¹¹6kJ/m²ISO 179/1eA
Charpy Impact (at 23°C, Unnotch Edgew 80*10*4 sp=62mm) ¹¹No breakkJ/m²ISO 179/1eU

Table 6 of 7

10 rows
CharacteristicValueUnit
Drying Temperature ⁷110 - 120°C
Drying Time ⁷2 - 4Hrs
Maximum Moisture Content ⁷0.02%
Melt Temperature ⁷245 - 260°C
Nozzle Temperature ⁷230 - 255°C
Front - Zone 3 Temperature ⁷240 - 260°C
Middle - Zone 2 Temperature ⁷235 - 250°C
Rear - Zone 1 Temperature ⁷230 - 240°C
Hopper Temperature ⁷40 - 60°C
Mold Temperature ⁷40 - 100°C

Table 7 of 7

13 rows
CharacteristicValueUnitMethod
UL Recognized (94-5VA Flame Class Rating) ᵖmin. 3mmUL 94
UL Recognized (94-5VB Flame Class Rating) ᵖmin. 2mmUL 94
UL Recognized (94V-0 Flame Class Rating) ᵖmin. 0.8mmUL 94
Glow Wire Ignitability Temperature (at 3.0 mm) ᵖ700°CIEC 60695-2-13
Glow Wire Ignitability Temperature (at 2.0 mm) ᵖ700°CIEC 60695-2-13
Glow Wire Ignitability Temperature (at 1.5 mm) ᵖ700°CIEC 60695-2-13
Glow Wire Ignitability Temperature (at 0.8 mm) ᵖ750°CIEC 60695-2-13
Glow Wire Flammability Index (at 3 mm) ᵖ960°CIEC 60695-2-12
Glow Wire Flammability Index (at 2 mm) ᵖ960°CIEC 60695-2-12
Glow Wire Flammability Index (at 1.5 mm) ᵖ960°CIEC 60695-2-12
Glow Wire Flammability Index (at 0.8 mm) ᵖ960°CIEC 60695-2-12
Oxygen Index (LOI) ᵖ31%ASTM D2863

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