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Harcryl® 1228 M

CAS Number
52628-03-2
Chemical Name
2-Hydroxyethyl methacrylate phosphate

Harcryl® 1228 M is a free acid phosphate ester of 2-HEMA (hydroxyethyl methacrylate). It is predominantly composed of the monoalkyl phosphate ester, making it easy to incorporate into a variety of polymer systems. The ratio of mono-alkyl to dialkyl phosphate makes Harcryl® 1228 M more hydrophilic than Harcryl® 1228. In addition, it is inhibited by the addition of 400 ppm hydroquinone.

Properties

Physical Form
Liquid

Identification

CASE Ingredients Features
Corrosion Resistance
CASE Ingredients Functions
Adhesion PromoterCoupling AgentMonomer

Product families

CASE Ingredients — Additives
  • Functional Additives
CASE Ingredients — Monomers & Intermediates
  • Monomers

Other characteristics

Brand
Harcryl®
Synonyms
2-Hydroxyethyl 2-methyl-2-propenoate phosphated
Functions
Adhesion Promoter, Coupling Agent, Monomer
Compatible Polymers & Resins
Acrylics, Polyurethanes (PU), Styrene Acrylics
Appearance
Yellow viscous liquid
Shelf LIfe
1 Year
Substrates

Metals Aluminum, Galvanized Steel, Iron-Phosphated Steel, Zinc-Phosphated Steel, Rolled Steel, and Stainless Steel.; Aluminum, Galvanized Steel, Iron-Phosphated Steel, Zinc-Phosphated Steel, Rolled Steel, and Stainless Steel.; Polymers Acrylic, Styrene/Acrylic, VEOVA/Acrylic, and Polyurethanes; Acrylic, Styrene/Acrylic, VEOVA/Acrylic, and Polyurethanes

Technology
CASE Ingredients
Key Attributes

Features:; Reactive methacrylic group; Phosphate active group; Promotes adhesion; Provides corrosion resistance; Benefits:; The phosphate functional group promotes adhesion to a variety of surfaces, reducing the need for pretreatments.; Improved adhesion saves time and reduces layers from the coating process.; Improved corrosion resistance due to the phosphate functional group reduces the need for additional inhibitors.; The acrylic backbone allows Harcryl® 1228 M to easily incorporate into many coating systems.

Chemical Inventories
  • AICS (Australia)
  • DSL (Canada)
  • ECL (Korea)
  • EINECS (EU)
  • ENCS (Japan)
  • IECSC (China)
  • NZIoC (New Zealand)
  • PICCS (Phillipines)
Usage Recommendations

Harcryl® 1228 M should not be used as a straight additive. As a monomer, it should be fed separately or in the monomer pre-mix. Do not mix with the initiator solution as hazardous polymerization may occur.

Compatible Polymers and Resins
  • Acrylics
  • Polyurethanes (PU)
  • Styrene Acrylics
Compatible Substrates and Surfaces
  • Concrete
  • Metal
Storage, Stability and Handling Information

Harcryl® 1228 M should be stored out of sunlight in stainless steel, lined, or plastic vessels. This product is listed as a DOT corrosive.

Technical data

Table 1 of 1

7 rows
CharacteristicValueUnit
Activitymin. 99%
Moisture Contentmax. 1%
Acid Number 1 (at pH 5.5)312.0mg KOH/g
Acid Number 2 (at pH 9.5)580 - 590mg KOH/g
pH (at 1% Aqueous)1.5 - 2.5—
Flash Pointmin. 93°C
Specific Gravity (at 25ºC)1.250 - 1.35—

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